1108678-13-2

Basic information

• Product Name: (2,6-diisopropylphenyl-N=)Mo(Cl)(OEt)(PMe₃)3
• CAS NO: 1108678-13-2
• Molecular Weight: 579.962
• Mol File: 1108678-13-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2,6-diisopropylphenyl-N=)Mo(Cl)(OEt)(PMe₃)3(CAS DataBase Reference)
• NIST Chemistry Reference: (2,6-diisopropylphenyl-N=)Mo(Cl)(OEt)(PMe₃)3(1108678-13-2)
• EPA Substance Registry System: (2,6-diisopropylphenyl-N=)Mo(Cl)(OEt)(PMe₃)3(1108678-13-2)

Safety Data

• Hazardous Substances Data: 1108678-13-2(Hazardous Substances Data)

Upstream product

• 1108678-07-4 (2,6-diisopropylphenyl-N=)Mo(H)(Cl)(PMe₃)3 
• 141-78-6 ethyl acetate 
• 64-17-5 ethanol 

Downstream Products

• 1108678-07-4 (2,6-diisopropylphenyl-N=)Mo(H)(Cl)(PMe₃)3 
• 72035-40-6 2-ethoxy-o-phenylene-1,3,2-dioxaborolane 

Relevant articles and documents

Imido-hydrido complexes of Mo(IV): Catalysis and mechanistic aspects of hydroboration reactions

Imido-hydrido complexes (ArN)Mo(H)(Cl)(PMe3)3 (1) and (ArN)Mo(H)2(PMe3)3 (2) (Ar = 2,6-diisopropylphenyl) catalyse a variety of hydroboration reactions, including the rare examples of addition of HBCat to nitriles to form bis(borylated) amines RCH2N(BCat)2. Stoichiometric reactivity of complexes 1 and 2 with nitriles and HBCat suggest that catalytic reactions proceed via a series of agostic borylamido and borylamino complexes. For complex 1, catalysis starts with addition of nitriles across the Mo-H bond to give (ArN)Mo(Cl)(NCHR)(PMe3)2; whereas for complex 2 stoichiometric reactions suggest initial addition of HBCat to form the agostic complex Mo(H)2(PMe3)3(η3-NAr-HBcat) (16).