111036-56-7

Basic information

• Product Name: 2-Benzenesulfinyl-6-tert-butyl-2-methyl-1-oxa-spiro[2.5]octane
• Synonyms: 2-Benzenesulfinyl-6-tert-butyl-2-methyl-1-oxa-spiro[2.5]octane
• CAS NO: 111036-56-7
• Molecular Weight: 306.469
• Mol File: 111036-56-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Benzenesulfinyl-6-tert-butyl-2-methyl-1-oxa-spiro[2.5]octane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Benzenesulfinyl-6-tert-butyl-2-methyl-1-oxa-spiro[2.5]octane(111036-56-7)
• EPA Substance Registry System: 2-Benzenesulfinyl-6-tert-butyl-2-methyl-1-oxa-spiro[2.5]octane(111036-56-7)

Safety Data

• Hazardous Substances Data: 111036-56-7(Hazardous Substances Data)

Upstream product

• 98-53-3 4-tercbutyl-cyclohexanone 
• 26910-40-7 1-chloroethyl phenyl sulfoxide 

Downstream Products

• 37881-09-7 1-acetyl-4-tert-butylcyclohex-1-ene 

Relevant articles and documents

A Novel Synthesis of Methylenecyclopropane Spiro-Linked with Cycloalkanes via a Cyclization of Allylic Epoxides and Its Application to a Synthesis of Fused 3-Methylfurans

Ring closure of allylic epoxides derived from 1-chloroalkyl phenyl sulfoxides and cyclic ketones with lithium diisopropylamide (LDA) in 3-Exo-Tet mode gave spiro-linked methylenecyclopropanes having a hydroxyl group in good yields.Oxidation of these compounds gave ketones, which were then treated with p-toluenesulfonic acid in 1,4-dioxane or DMSO at 100 deg C to give fused 3-methylfurans in good overall yields.This procedure was applied to a synthesis of menthofuran from 4-methylcyclohexanone.