111203-04-4

Basic information

• Product Name: C₂₄H₄₃FNSi^(1-)*3C₄H₈O*Li⁽¹⁺⁾
• CAS NO: 111203-04-4
• Molecular Weight: 615.958
• Mol File: 111203-04-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₄H₄₃FNSi^(1-)*3C₄H₈O*Li⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₄H₄₃FNSi^(1-)*3C₄H₈O*Li⁽¹⁺⁾(111203-04-4)
• EPA Substance Registry System: C₂₄H₄₃FNSi^(1-)*3C₄H₈O*Li⁽¹⁺⁾(111203-04-4)

Safety Data

• Hazardous Substances Data: 111203-04-4(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 102745-20-0 (Fluoro-diisopropyl-silanyl)-(2,4,6-tri-tert-butyl-phenyl)-amine 

Downstream Products

• 92411-30-8 2,2,4,4,6,6-hexaisopropylcyclotrisiloxane 
• 136158-46-8 [1-Phenyl-meth-(E)-ylidene]-(2,4,6-tri-tert-butyl-phenyl)-amine 

Relevant articles and documents

From Lithiated Aminofluorosilanes to Mono- and Dimeric Iminosilanes

Depending on the solvent and the bulkiness of the substituents, lithiated aminofluorosilanes are dimers, monomers, or LiF-adducts of iminosilanes.In the crystal structure of the dimeric lithium derivative of di-tert-butyl(tert-butylamino)fluorosilane, each lithium atom is coordinated by one fluorine and two nitrogen atoms.LiF-elimination leads - if sterically possible - to dimerisation.The limits of dimerisation are reached with the dimer diisopropyl(tri-tert-butylphenylimino)silane, for which the crystal structure analysis shows severe steric distortions.Fluorine-chlorine-exchange occurs in reactions of lithiated (tri-tert-butylphenylimino)fluorosilanes with Me3SiCl.Iminosilanes are obtained by thermal LiCl-elimination from the resulting salts. - Keywords: Aminofluorosilanes, Lithium Salts, Cyclisation, Iminosilanes, Crystal Structure