111233-40-0

Basic information

• Product Name: 1-Naphthacenecarboxylicacid,4-[[2,6-dideoxy-4-O-[2,6-dideoxy-4-O-[(2R,6S)-tetrahydro-6-methyl-5-oxo-2H-pyran-2-yl]-a-L-lyxo-hexopyranosyl]-a-L-lyxo-hexopyranosyl]oxy]-2-ethyl-1,2,3,4,6,11-hexahydro-2,5,7,10-tetrahydroxy-6,11-dioxo-,methyl ester, (1R,2R,4S)- (9CI)
• Synonyms: 1-Naphthacenecarboxylicacid,4-[[2,6-dideoxy-4-O-[2,6-dideoxy-4-O-[(2R-trans)-tetrahydro-6-methyl-5-oxo-2H-pyran-2-yl]-a-L-lyxo-hexopyranosyl]-a-L-lyxo-hexopyranosyl]oxy]-2-ethyl-1,2,3,4,6,11-hexahydro-2,5,7,10-tetrahydroxy-6,11-dioxo-,methyl ester, [1R-(1a,2b,4b)]-; Ciclamycin 0
• CAS NO: 111233-40-0
• Molecular Formula: C40H48 O17
• Molecular Weight: 800.811
• Mol File: 111233-40-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Naphthacenecarboxylicacid,4-[[2,6-dideoxy-4-O-[2,6-dideoxy-4-O-[(2R,6S)-tetrahydro-6-methyl-5-oxo-2H-pyran-2-yl]-a-L-lyxo-hexopyranosyl]-a-L-lyxo-hexopyranosyl]oxy]-2-ethyl-1,2,3,4,6,11-hexahydro-2,5,7,10-tetrahydroxy-6,11-dioxo-,methyl ester, (1R,2R,4S)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Naphthacenecarboxylicacid,4-[[2,6-dideoxy-4-O-[2,6-dideoxy-4-O-[(2R,6S)-tetrahydro-6-methyl-5-oxo-2H-pyran-2-yl]-a-L-lyxo-hexopyranosyl]-a-L-lyxo-hexopyranosyl]oxy]-2-ethyl-1,2,3,4,6,11-hexahydro-2,5,7,10-tetrahydroxy-6,11-dioxo-,methyl ester, (1R,2R,4S)- (9CI)(111233-40-0)
• EPA Substance Registry System: 1-Naphthacenecarboxylicacid,4-[[2,6-dideoxy-4-O-[2,6-dideoxy-4-O-[(2R,6S)-tetrahydro-6-methyl-5-oxo-2H-pyran-2-yl]-a-L-lyxo-hexopyranosyl]-a-L-lyxo-hexopyranosyl]oxy]-2-ethyl-1,2,3,4,6,11-hexahydro-2,5,7,10-tetrahydroxy-6,11-dioxo-,methyl ester, (1R,2R,4S)- (9CI)(111233-40-0)

Safety Data

• Hazardous Substances Data: 111233-40-0(Hazardous Substances Data)

Upstream product

• 129985-41-7 7-O-<4-O-<4-O-(2,3,6-trideoxy-α-L-glycero-hexopyranosid-4-ulosyl)-2,6-dideoxy-3-O-(trimethylsilyl)-α-L-lyxo-hexopyranosyl>-2,6-dideoxy-2-iodo-3-O-(trimethylsilyl)-α-L-galactopyranosyl>-ε-pyrromycinone 
• 129985-41-7 7-O-<4-O-<4-O-(2,3,6-trideoxy-α-L-glycero-hexopyranosid-4-ulosyl)-2,6-dideoxy-3-O-(trimethylsilyl)-α-L-lyxo-hexopyranosyl>-2,6-dideoxy-2-iodo-3-O-(trimethylsilyl)-α-L-talopyranosyl>-ε-pyrromycinone 
• 130010-91-2 7-O-<4-O-<4-O-(2,3,6-trideoxy-α-L-glycero-hexopyranosid-4-ulosyl)-2,6-dideoxy-α-L-lyxo-hexopyranosyl>-2,6-dideoxy-2-iodo-3-O-(trimethylsilyl)-α-L-talopyranosyl>-ε-pyrromycinone 
• 230634-87-4 <(2,3,6-trideoxy-4-ulo-α-L-hexopyranosyl)-(1->4)-<2,6-dideoxy-3-O-(4-methoxybenzyl)-α-L-galactopyranosyl>>-(1->4)-2,6-dideoxy-3-O-(4-methoxybenzyl)-1-(2,6-dichlorophenylsulfinyl)-α-L-galactopyranoside 
• 21288-61-9 Epsilon-pyrromycinone 
• 167012-88-6 7-O-<(2,3,6-trideoxy-4-ulo-α-L-hexopyranosyl)-(1->4)-<2,6-dideoxy-3-O-(4-methoxybenzyl)-α-L-galactopyranosyl>-(1->4)-2,6-dideoxy-3-O-(4-methoxybenzyl)-1-(2,6-dichlorophenylsulfinyl)-α-L-galactopyranosyl>-ε-pyrromycinone 
• 129985-42-8 7-O-<4-O-<4-O-(2,3,6-trideoxy-α-L-glycero-hexopyranosid-4-ulosyl)-2,6-dideoxy-α-L-lyxo-hexopyranosyl>-2,6-dideoxy-2-iodo-α-L-galactopyranosyl>-ε-pyrromycinone 
• 129985-42-8 7-O-<4-O-<4-O-(2,3,6-trideoxy-α-L-glycero-hexopyranosid-4-ulosyl)-2,6-dideoxy-α-L-lyxo-hexopyranosyl>-2,6-dideoxy-2-iodo-α-L-talopyranosyl>-ε-pyrromycinone 
• 129985-41-7 7-O-<4-O-<4-O-(2,3,6-trideoxy-α-L-glycero-hexopyranosid-4-ulosyl)-2,6-dideoxy-3-O-(trimethylsilyl)-α-L-lyxo-hexopyranosyl>-2,6-dideoxy-2-iodo-3-O-(trimethylsilyl)-β-L-galactopyranosyl>-ε-pyrromycinone 
• 129985-42-8 C₄₀H₄₇IO₁₇ 

Relevant articles and documents

Scavenging byproducts in the sulfoxide glycosylation reaction: Application to the synthesis of ciclamycin 0

We have developed a direct and efficient route for the synthesis of ciclamycin 0 using the sulfoxide glycosylation reaction to form the glycosidic linkages. In the course of completing the synthesis of ciclamycin 0, we developed new glycosylation conditions that improve the outcome of the sulfoxide reaction. The conditions involve the addition of agents that scavenge phenylsulfenyl triflate, a highly reactive byproduct that forms following activation of anomeric sulfoxides with triflic anhydride.