111289-19-1

Basic information

• Product Name: dichloro-bis-(4-methyl-phenacyl)-λ⁴-selane
• Synonyms: dichloro-bis-(4-methyl-phenacyl)-λ⁴-selane
• CAS NO: 111289-19-1
• Molecular Weight: 416.206
• Mol File: 111289-19-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: dichloro-bis-(4-methyl-phenacyl)-λ⁴-selane(CAS DataBase Reference)
• NIST Chemistry Reference: dichloro-bis-(4-methyl-phenacyl)-λ⁴-selane(111289-19-1)
• EPA Substance Registry System: dichloro-bis-(4-methyl-phenacyl)-λ⁴-selane(111289-19-1)

Safety Data

• Hazardous Substances Data: 111289-19-1(Hazardous Substances Data)

Upstream product

• 122-00-9 para-methylacetophenone 
• 60-29-7 diethyl ether 

Downstream Products

• 4209-24-9 p-methylphenacyl chloride 
• 125732-00-5 2,2-Dichloro-2-(2-oxo-2-p-tolyl-ethylselanyl)-1-p-tolyl-ethanone 
• 125731-87-5 C₁₈H₁₇Cl₃O₂Se 
• 111289-31-7 [5-(4-Methyl-benzoyl)-selenophen-2-yl]-p-tolyl-methanone 
• 117374-99-9 (3R,4S)-3,4-Di-p-tolyl-tetrahydro-selenophene-3,4-diol 
• 117375-02-7 3,4-Di-p-tolyl-selenophene 
• 75416-81-8 4,4'-(buta-1,3-diene-2,3-diyl)bis(methylbenzene) 
• 120801-17-4 2-Chloro-2-(2-oxo-2-p-tolyl-ethylselanyl)-1-p-tolyl-ethanone 
• 111289-24-8 bis-(4-methyl-phenacyl)-selenide 

Relevant articles and documents

PUMMERER-LIKE REACTION OF SELENIUM(IV)-DICHLORIDES. SYNTHESIS OF α-CHLORO-α-PHENYLSELENENYLKETONES AND α,α-DICHLORO-α-PHENYLSELENENYLKETONES

Selenium(IV)-dichlorides 1, readily available by treatment of methyl ketones with phenylselenium trichloride or selenium tetrachloride, were treated in methylene chloride with pyridine to give α-chloroselenides 2 in a Pummerer-like reaction.Sulfuryl chlor

A Seleno-Pummerer Rearrangement of Haloselenuranes

When heated or treated with triethylamine in tetrahydrofuran, diacetonyl- and diphenacylselenium dichlorides and their derivatives undergo seleno-Pummerer rearrangement to give the corresponding α-chloro selenides in good yields.