111360-78-2

Basic information

• Product Name: <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteine
• CAS NO: 111360-78-2
• Molecular Weight: 668.765
• Mol File: 111360-78-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteine(CAS DataBase Reference)
• NIST Chemistry Reference: <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteine(111360-78-2)
• EPA Substance Registry System: <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteine(111360-78-2)

Safety Data

• Hazardous Substances Data: 111360-78-2(Hazardous Substances Data)

Upstream product

• 2544-31-2 S-(4-methoxybenzyl)-L-cysteine 
• 58635-29-3 N-(4-methoxybenzyloxycarbonyl)-α-(4-methoxybenzylester)-δ-L-α-aminoadipic acid 

Downstream Products

• 138246-03-4 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-L-2-amino-<3,4-2H2>pent-4-enoic acid benzhydryl ester 
• 138246-03-4 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-D-3R-2-amino-<3,4-2H2>pent-4-enoic acid benzhydryl ester 
• 138246-03-4 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-L-2-amino-<3-2H1>pent-4-enoic acid benzhydryl ester 
• 138246-03-4 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-D-3RS-2-amino-<3-2H1>pent-4-enoic acid benzhydryl ester 
• 138246-42-1 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-L-2-amino-(E)-<3,3,4,5-2H4>pent-4-enoic acid benzhydryl ester 
• 138246-42-1 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-D-2-amino-(E)-<3,3,4,5-2H4>pent-4-enoic acid benzhydryl ester 
• 138246-03-4 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-L-2-amino-<3,4-2H2>pent-4-enoic acid benzhydryl ester 
• 138246-03-4 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-D-3S-2-amino-<3,4-2H2>pent-4-enoic acid benzhydryl ester 
• 138246-40-9 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-L-2-amino-<3,3-2H2>pent-4-enoic acid benzhydryl ester 
• 138246-40-9 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-D-2-amino-<3,3-2H2>pent-4-enoic acid benzhydryl ester 
• 138246-15-8 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-L-2-aminopent-4-enoic acid benzhydryl ester 
• 138246-15-8 <(N-4-methoxybenzyloxycarbonyl)-(α-4-methoxybenzyl)-δ-(L-α-aminoadipoyl)>-S-(4-methoxybenzyl)-L-cysteinyl-D-2-aminopent-4-enoic acid benzhydryl ester 
• 133388-80-4 N-4-methoxybenzyloxycarbonyl-α-4-methoxybenzylester-δ-L-α-aminodipoyl-S-4-methoxybenzyl-L-cysteinyl-D-<3-2H>valine benzhydrylester 

Relevant articles and documents

NEW PENICILLINS FROM ISOPENICILLIN N SYNTHASE.

The three tripeptides δ-L-α-aminoadipoyl-L-cysteinyl-D-propargylglycine, δ-L-α-aminoadipoyl-L-cysteinyl-D-cyanoalanine and δ-L-α-aminoadipoyl-L-cysteinyl-D--norvaline were synthesised and incubated with the enzyme Isopenicillin N Synthase (IPNS).All incubation mixtures contained biologically active products, and led to the isolation of four new penicillins (β-ethyl, α-acetylenic, α- and β-nitrile) following purification by reverse phase HPLC.The stereochemistries of formation of monosubstituted penicillins with IPNS are rationalised.