111409-83-7Relevant articles and documents
Towards the synthesis of tetraethynylallene
Lange, Tim,Van Loon, Jan-Dirk,Tykwinski, Rik R.,Schreiber, Martin,Diederich, Francois
, p. 537 - 550 (1996)
Synthetic routes towards tetraethynylallene (4), a perethynylated modular entity for the construction of three-dimensional all-carbon networks and all-carbon backbone polymers with a stepladder or helical structure, are presented. They comprise propargylic rearrangements, cyclopropanations with carbenes, Peterson and Wittig-type olefinations, and alkylations of ketones with α-bromovinyl anions.