111492-56-9

Basic information

• Product Name: 5,7-Dihydroxy-6-((S)-2-methyl-butyryl)-4-propyl-chromen-2-one
• CAS NO: 111492-56-9
• Molecular Weight: 304.343
• Mol File: 111492-56-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5,7-Dihydroxy-6-((S)-2-methyl-butyryl)-4-propyl-chromen-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5,7-Dihydroxy-6-((S)-2-methyl-butyryl)-4-propyl-chromen-2-one(111492-56-9)
• EPA Substance Registry System: 5,7-Dihydroxy-6-((S)-2-methyl-butyryl)-4-propyl-chromen-2-one(111492-56-9)

Safety Data

• Hazardous Substances Data: 111492-56-9(Hazardous Substances Data)

Upstream product

• 98216-09-2 (S)-(-)-5,7-dihydroxy-8-(2-methylbutyryl)-4-propylcoumarin 
• 870-63-3 prenyl bromide 

Relevant articles and documents

Synthesis of the Mammea Coumarins. Part 4. Stereochemical and Regiochemical Studies, and Synthesis of (-)-Mammea B/BB

Acylation of phloroglucinol with (S)-2-methylbutyryl chloride followed by Pechmann condensation with ethyl 3-oxohexanoate, or acylation of 5,7-dihydroxy-4-propylcoumarin with (S)-2-methylbutyryl chloride gave an 8-(S)-acylcoumarin that was C-alkylated to afford natural (-)-mammea B/BB: the configuration of the 2-methylbutyryl moiety in the natural coumarins was thus demonstrated to be (S)-Surangin B was likewise prepared as a mixture of 1'S, 2''S)- and (1'R, 2''S)-stereoisomers.The crystal structure and conformation of a 6-acylcoumarin that establishes the orientation of other synthetic coumarins is reported.