112-57-2 Usage
Description
1,4,7,10,13-Pentaazatridecane, also known as Tetraethylenepentamine, is a viscous liquid with a color ranging from colorless to green-yellow. It is slightly less dense than water and has vapors that are heavier than air. 1,4,7,10,13-Pentaazatridecane is corrosive to the eyes, skin, mouth, throat, and stomach, and its vapors can cause irritation to the eyes and upper respiratory tract. It has a flash point of 325°F.
Uses
Used in Chemical Industry:
1,4,7,10,13-Pentaazatridecane is used as a solvent for sulfur, acid gases, and various resins and dyes due to its ability to dissolve these substances effectively.
Used in Manufacturing Industry:
1,4,7,10,13-Pentaazatridecane is used as a saponifying agent for acidic materials, which helps in the production of soaps and detergents.
Used in Rubber Industry:
1,4,7,10,13-Pentaazatridecane is used in the manufacture of synthetic rubber, contributing to the development of various rubber products.
Used in Automotive Industry:
1,4,7,10,13-Pentaazatridecane is used as a dispersant in motor oils, enhancing the performance and longevity of the oil.
Used in Oil Industry:
1,4,7,10,13-Pentaazatridecane is used as an intermediate for oil additives, improving the properties and performance of various oil products.
Air & Water Reactions
Soluble in water. Hygroscopic.
Reactivity Profile
1,4,7,10,13-Pentaazatridecane is hygroscopic. 1,4,7,10,13-Pentaazatridecane can react with oxidizing materials and strong acids. 1,4,7,10,13-Pentaazatridecane may attack some forms of plastics.
Hazard
Strong irritant to eyes and skin.
Health Hazard
Inhalation may cause nausea and slight irritation; compound is a sensitizer, and prolonged contact may cause asthma. Ingestion can cause burns of mouth, esophagus, and possibly stomach. Contact with eyes or skin may cause burns. Repeated skin contact may cause dermatitis.
Fire Hazard
Special Hazards of Combustion Products: Ammonia and toxic oxides of nitrogen may form in fires.
Safety Profile
Poison by ingestion and intravenous routes. Moderately toxic by skin contact. Mutation data reported. A corrosive irritant to skin, eyes, and mucous membranes. Combustible when exposed to heat or flame. Can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits toxic fumes of NOx.
Potential Exposure
Tetraethylenepentamine is used as a solvent for resins and dyes, in manufacture of synthetic rubber; and intermediate for oil additives; in papermaking.
Shipping
UN2320 Tetraethylenepentamine, Hazard class: 8; Labels: 8-Corrosive material.
Purification Methods
Distil the amine under vacuum. Also purify via its penta hydrochloride, nitrate or sulfate. Jonassen, Frey and Schaafsma [J Phys Chem 61 504 1957] cooled a solution of 150g of the base in 300mL of 95% EtOH, and added dropwise 180mL of conc HCl, keeping the temperature below 20o. The white precipitate was filtered off, crystallised three times from EtOH/water, then washed with diethyl ether and dried by suction. Reilley and Holloway [J Am Chem Soc 80 2917 1958], starting with a similar solution cooled to 0o, added slowly (keeping the temperature below 10o) a solution of 4.5g-moles of HNO3 in 600mL of aqueous 50% EtOH (also cooled to 0o). The precipitate was filtered by suction, recrystallised five times from aqueous 5% HNO3, then washed with acetone and absolute EtOH and dried at 50o. [For purification via the sulfate see Reilley and Vavoulis (Anal Chem 31 243 1959), and for an additional purification step using the Schiff base with benzaldehyde see Jonassen et al. J Am Chem Soc 79 4279 1957]. [Beilstein 4 IV 1244.]
Incompatibilities
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. This chemical is strongly alkaline; reacts with acids.
Check Digit Verification of cas no
The CAS Registry Mumber 112-57-2 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 2 respectively; the second part has 2 digits, 5 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 112-57:
(5*1)+(4*1)+(3*2)+(2*5)+(1*7)=32
32 % 10 = 2
So 112-57-2 is a valid CAS Registry Number.
InChI:InChI=1/C8H23N5/c9-1-3-11-5-7-13-8-6-12-4-2-10/h11-13H,1-10H2/p+5
112-57-2Relevant articles and documents
Complexes of tetraethylenepentamine with iron(II) and iron(III). An iron(II) carbonyl derivative
Melby, L. Russell
, p. 2186 - 2188 (1970)
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TWO-STEP PROCESS FOR CONVERTING CYCLIC ALKYLENE UREAS INTO THEIR CORRESPONDING ALKYLENE AMINES
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Page/Page column 22-24, (2019/02/25)
The invention pertains to a process for converting cyclic alkyleneureas into their corresponding alkyleneamines, comprising - in a first step converting cyclic alkyleneureas into their corresponding alkyleneamines by reacting cyclic alkyleneureas in the liquid phase with water with removal of CO2, so as to convert between 5 mole% and 95 mole% of alkyleneurea moieties in the feedstock to the corresponding amines, and - in a second step adding an inorganic base and reacting cyclic alkylene ureas remaining from the first step with the inorganic base to convert them partially or completely into their corresponding alkyleneamines. It has been found that the two-step process of the present invention makes it possible to still obtain a high conversion of cyclic alkyleneureas, while using substantially less strong inorganic base. The process according to the invention also shows a higher selectivity to amines than the prior art process.
METHOD FOR PRODUCING POLYETHYLENE POLYAMINES
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Paragraph 0051-0052; 0059, (2018/02/27)
PROBLEM TO BE SOLVED: To provide a method for producing polyethylene polyamines with high selectivity and high yield. SOLUTION: In the presence of a solid acid catalyst, ethylene amines and aziridine are reacted with each other so that an equivalent of ethylene amines is 3 equivalents or more and 30 equivalents or less relative to aziridine. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPOandINPIT