112044-02-7

Basic information

• Product Name: pentacarbonyl{(2-chlorophenyl)(N,N-dimethylamino)carbene}chromium⁽⁰⁾
• Synonyms: pentacarbonyl{(2-chlorophenyl)(N,N-dimethylamino)carbene}chromium⁽⁰⁾
• CAS NO: 112044-02-7
• Molecular Weight: 359.686
• Mol File: 112044-02-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: pentacarbonyl{(2-chlorophenyl)(N,N-dimethylamino)carbene}chromium⁽⁰⁾(CAS DataBase Reference)
• NIST Chemistry Reference: pentacarbonyl{(2-chlorophenyl)(N,N-dimethylamino)carbene}chromium⁽⁰⁾(112044-02-7)
• EPA Substance Registry System: pentacarbonyl{(2-chlorophenyl)(N,N-dimethylamino)carbene}chromium⁽⁰⁾(112044-02-7)

Safety Data

• Hazardous Substances Data: 112044-02-7(Hazardous Substances Data)

Upstream product

• 6526-67-6 N,N-dimethyl-o-chlorobenzamide 

Relevant articles and documents

Synthesis of (aminocarbene)chromium(0) complexes by the reaction of Na2Cr(CO)5 with amides in the presence of trimethylsilyl chloride

Addition of trimethylsilyl chloride to a mixture of Na2Cr(CO)5 and a variety of tertiary amides produced (aminocarbene)pentacarbonylchromium(0) complexes in fair to excellent yield. The procedure developed is a rapid, convenient, one-pot process and permits the synthesis of carbene complexes not readily available by other synthetic routes. These carbene complexes have potential application in the synthesis of β-lactams and α-amino acids.