112075-27-1

Basic information

• Product Name: cis/trans-5-phenyl-4-(S-phenyl-N-tosylsulfonimidoyl)-5-trifluoromethyl-2-oxazoline
• CAS NO: 112075-27-1
• Molecular Weight: 508.542
• Mol File: 112075-27-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis/trans-5-phenyl-4-(S-phenyl-N-tosylsulfonimidoyl)-5-trifluoromethyl-2-oxazoline(CAS DataBase Reference)
• NIST Chemistry Reference: cis/trans-5-phenyl-4-(S-phenyl-N-tosylsulfonimidoyl)-5-trifluoromethyl-2-oxazoline(112075-27-1)
• EPA Substance Registry System: cis/trans-5-phenyl-4-(S-phenyl-N-tosylsulfonimidoyl)-5-trifluoromethyl-2-oxazoline(112075-27-1)

Safety Data

• Hazardous Substances Data: 112075-27-1(Hazardous Substances Data)

Upstream product

• 434-45-7 2,2,2-Trifluoroacetophenone 
• 89539-02-6 (-)-S-phenyl-N-tosylsulfonimimidoylmethyl isocyanide 

Relevant articles and documents

SYNTHESIS OF CHIRAL SULFONYLMETHYL ISOCYANIDES, AND COMPARISON OF THEIR PROPENSITIES IN ASYMMETRIC INDUCTION REACTIONS WITH ACETOPHENONES

Seven chiral analogues of tosylmethyl isocyanide (TosMIC) were synthesized in order to investigate and compare their ability to achieve asymmetric induction in base mediated reactions with acetophenone and trifluoracetophenone.Acid hydrolysis of the intermediate 2-oxazolines (10 and 11) gave optically active α-hydroxy aldehydes (12 and 13).