112197-45-2Relevant articles and documents
Rh(I)/(III)-N-Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio- and Stereoselectivity in the Hydrosilylation of Alkynes
Atwi, Boshra,Bauer, Matthias,Buchmeiser, Michael R.,Frey, Wolfgang,Nowakowski, Michal,Panyam, Pradeep K. R.,Ziegler, Felix
supporting information, p. 17220 - 17229 (2021/11/10)
Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp=pentamethylcyclopentadienyl, NHC=N-heterocyclic carbene=pyrid-2-ylimidazol-2-ylidene (Py?Im), thiophen-2-ylimidazol-2-ylidene) are presented. Selected catalysts were selectively immobilized inside the mesopores
Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex: Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes
Andavan, Gurusamy Thangavelu Senthil,Bauer, Eike B.,Letko, Christopher S.,Hollis, T. Keith,Tham, Fook S.
, p. 5938 - 5947 (2007/10/03)
1,3-Bis(3-butylimidazolium-1-yl)benzene diiodide (1) was reacted with Li(2,2,6,6-tetramethylpiperidine) yielding the free bis-carbene, 1,3-bis(3-butylimidazol-2-ylidene-1-yl)benzene (3), which has been spectroscopically characterized. Combining the free b