112321-64-9Relevant articles and documents
Diradical Rearrangements: An Unusual 1,2-Shift in a Photochemically Generated 1,3-Diradical. Mechanistic and Exploratory Organic Photochemistry
Zimmerman, Howard E.,Kamath, Ajit P.
, p. 900 - 911 (2007/10/02)
The triplet photochemistry of 2,5-dianisyl-2,5-dimethyl-hex-3-ene was explored in a study of the behavior of diradical species occuring in the di-?-methane rearrangement.It was observed that the penultimate species, the 1,3-diradical, closes more rapidly