112402-80-9

Basic information

• Product Name: Benzenamine, 3-[[(tributylstannyl)oxy]carbonyl]-
• CAS NO: 112402-80-9
• Molecular Formula: C19H33NO2Sn
• Molecular Weight: 426.187
• Mol File: 112402-80-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenamine, 3-[[(tributylstannyl)oxy]carbonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 3-[[(tributylstannyl)oxy]carbonyl]-(112402-80-9)
• EPA Substance Registry System: Benzenamine, 3-[[(tributylstannyl)oxy]carbonyl]-(112402-80-9)

Safety Data

• Hazardous Substances Data: 112402-80-9(Hazardous Substances Data)

Upstream product

• 1461-22-9 tributyltin chloride 
• 1709-44-0 m-aminobenzaldehyde 

Downstream Products

• 1218758-83-8 tributylstannyl 3-[1-pyridin-2-ylmethylidene]benzoate 

Relevant articles and documents

N-Heterocyclic carbene catalyzed oxidative stannylation of aldehydes: A facile entry to organotin(IV) carboxylates

A simple protocol is described for the oxidative transformation of aldehydes to the corresponding organotin(IV) carboxylates in high yields (up to 90%) that utilizes atmospheric O2 as the sole oxidant, N-heterocyclic carbene as catalyst (at 10 mol %), and tributyl tin chloride as stannylating agent. The uniqueness of the reaction lies in the direct conversion of aldehydes to the corresponding organotin(IV) carboxylates via stannylation of carboxylic acids, generated from the reaction of a Breslow intermediate with O2.