112472-86-3

Basic information

• Product Name: Hexaacetyl-4-formyl
• CAS NO: 112472-86-3
• Molecular Weight: 626.568
• Mol File: 112472-86-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Hexaacetyl-4-formyl(CAS DataBase Reference)
• NIST Chemistry Reference: Hexaacetyl-4-formyl(112472-86-3)
• EPA Substance Registry System: Hexaacetyl-4-formyl(112472-86-3)

Safety Data

• Hazardous Substances Data: 112472-86-3(Hazardous Substances Data)

Upstream product

• 11044-25-0 Acetic acid (1S,5S)-7-acetoxymethyl-1-((3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,7a-tetrahydro-cyclopenta[c]pyran-5-yl ester 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 27530-67-2 scandoside methyl ester 

Relevant articles and documents

APPLICATION OF THE VILSMEIER FORMYLATION IN THE SYNTHESIS OF 11-(13)C LABELLED IRIDOIDS

The Vilsmeier reaction was utilized for the introduction of C-11 into iridoid glucosides, Aucubin hexaacetate (3a). 6,10-dideoxy aucubin tetraacetate (6a) and 8(S)-6,10-dideoxy-7,8-dihydro aucubin tetraacetate (7a) were used as substrates for the reaction. 6a and 7a were prepared by catalytic transfer hydrogenation of 3a with formic acid and Pd/C.The Vilsmeier reaction conditions were optimized with regard to the economic use of --DMF in the synthesis of -iridotrialglucoside (9).Remarcably, 5percent of the label in the product turned out to be situated at C-3.