112497-22-0

Basic information

• Product Name: (3S,5S)-6-<(benzyloxy)methyl>-4-<1-(tert-butyldiphenylsilyloxy)ethyl>-2,2-dimethyl-1,3-dioxacyclohexane
• Synonyms: (3S,5S)-6-<(benzyloxy)methyl>-4-<1-(tert-butyldiphenylsilyloxy)ethyl>-2,2-dimethyl-1,3-dioxacyclohexane
• CAS NO: 112497-22-0
• Molecular Weight: 518.769
• Mol File: 112497-22-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (3S,5S)-6-<(benzyloxy)methyl>-4-<1-(tert-butyldiphenylsilyloxy)ethyl>-2,2-dimethyl-1,3-dioxacyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,5S)-6-<(benzyloxy)methyl>-4-<1-(tert-butyldiphenylsilyloxy)ethyl>-2,2-dimethyl-1,3-dioxacyclohexane(112497-22-0)
• EPA Substance Registry System: (3S,5S)-6-<(benzyloxy)methyl>-4-<1-(tert-butyldiphenylsilyloxy)ethyl>-2,2-dimethyl-1,3-dioxacyclohexane(112497-22-0)

Safety Data

• Hazardous Substances Data: 112497-22-0(Hazardous Substances Data)

Upstream product

• 112497-18-4 (4R,6S)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxane-4-carbaldehyde 
• 112497-17-3 (4S,6S)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxane-4-carbaldehyde 
• 112497-13-9 (3S)-4-benzyloxy-3-tert-butyldimethylsilyloxybutanal 
• 112497-15-1 (1S,3S)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-1-[1,3]dithian-2-yl-butan-1-ol 
• 253431-95-7 ((S)-1-Benzyloxymethyl-2-[1,3]dithian-2-yl-ethoxy)-tert-butyl-dimethyl-silane 
• 112497-16-2 (4S,6S)-4-Benzyloxymethyl-6-[1,3]dithian-2-yl-2,2-dimethyl-[1,3]dioxane 
• 112497-10-6 (R)-1-Benzyloxy-3-((R)-toluene-4-sulfinyl)-propan-2-ol 
• 112497-09-3 1-Benzyloxy-3-((R)-toluene-4-sulfinyl)-propan-2-one 
• 112497-11-7 (R)-1-Benzyloxy-3-p-tolylsulfanyl-propan-2-ol 
• 112497-20-8 (4S,6R)-4-Benzyloxymethyl-2,2-dimethyl-6-vinyl-[1,3]dioxane 
• 112497-12-8 (S)-1-Benzyloxy-3-[1,3]dithian-2-yl-propan-2-ol 
• 2930-05-4 (S)-benzyl glycidyl ether 
• 30379-55-6 benzyloxyacetic acid 
• 138747-45-2 (3S,4S,5R)-tert-butyl <6-(benzyloxy)-4,5-epoxy-3-hydroxy>hexanoate 

Downstream Products

• 92757-18-1 (4R,6S)-6-(benzyloxy)methyl-4-hydroxy-tetrahydro-2-pyrone 
• 92757-83-0 (3R,5S)-6-Benzyloxy-3,5-dihydroxy-hexanoic acid 
• 151140-37-3 ((4R,6S)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-acetic acid 
• 112497-24-2 (S)-((4R,6S)-6-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-(2-{(4S,6S)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxan-4-ylmethyl}-[1,3]dithian-2-yl)-methanol 
• 112497-23-1 Trifluoro-methanesulfonic acid (4S,6S)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxan-4-ylmethyl ester 
• 214345-66-1 ((4S,6S)-6-(2-(tert-butyldiphenylsilyloxy)ethyl)-2,2-dimethyl-1,3-dioxan-4-yl)methanol 
• 112497-21-9 (4S,6S)-6-<(benzyloxy)methyl>-4-(2-hydroxyethyl)-2,2-dimethyl-1,3-dioxacyclohexane 

Relevant articles and documents

A first convergent synthesis of the polyolic fragment of the antifungal pentaene macrolide strevertene A

The C(4-14) polyolic segment of antifungal macrolide strevertenes has been synthesized for the first time in protected form, incorporating four stereogenic centers. The synthetic strategy developed is based on the connection of two subunits prepared start

Diastereoselection in the addition of enolates to chiral α,β-epoxyaldehydes

The stereochemistry of addition of lithium enolates to the α,β-epoxyaldehydes 1z-3 has been investigated. Moderate to high diastereoselectivity (up to 13:1) is obtained in favour of the anti isomer, which is explained by the Felkin-Anh model for asymmetric induction.