112635-25-3

Basic information

• Product Name: 1H-Indene-2-acetic acid, 2,3-dihydro-1-oxo-, methyl ester
• CAS NO: 112635-25-3
• Molecular Formula: C12H12O3
• Molecular Weight: 204.225
• Mol File: 112635-25-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 1H-Indene-2-acetic acid, 2,3-dihydro-1-oxo-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Indene-2-acetic acid, 2,3-dihydro-1-oxo-, methyl ester(112635-25-3)
• EPA Substance Registry System: 1H-Indene-2-acetic acid, 2,3-dihydro-1-oxo-, methyl ester(112635-25-3)

Safety Data

• Hazardous Substances Data: 112635-25-3(Hazardous Substances Data)

Upstream product

• 96-32-2 bromoacetic acid methyl ester 
• 83-33-0 inden-1-one 
• 4471-33-4 cis-3,3a,4,8b-tetrahydro-2H-indeno<1,2-b>furan-2-one 
• 1001351-00-3 (N,N)-diisopropyl 2-iodophenylacetamide 
• 136911-07-4 methyl 2′-allyl-2-phenylacetate 
• 1381845-07-3 (N,N)-diisopropyl 2-allylphenylacetamide 
• 18698-96-9 o-iodophenylacetic acid 
• 62300-07-6 o-iodophenylacetyl chloride 
• 66370-75-0 methyl (2-iodophenyl)acetate 
• 67-56-1 methanol 
• 7103-80-2 (1-oxo-2-indanyl)acetic acid 
• 131251-43-9 1-iodo-2-(prop-2-yn-1-yl)benzene 
• 201230-82-2 carbon monoxide 
• 179735-85-4 (E)-4-(2-Iodo-phenyl)-but-2-enoic acid methyl ester 

Downstream Products

• 1381844-79-6 1-(4-chlorophenyl)-3,3a,4,8b-tetrahydroindeno[1,2-b]pyrrol-2-one 

Relevant articles and documents

Divergent Access to (1,1) and (1,2)-Azidolactones from Alkenes using Hypervalent Iodine Reagents

A versatile synthesis of azidolactones through azidation and cyclization of carboxylic acids onto alkenes has been developed. Based on either photoredox or palladium catalysis, (1,1) and (1,2) azido lactones can be selectively synthesized. The choice of catalyst and benziodoxol(on)e reagent serving as azide source was essential to initiate either a radical or Lewis acid mediated process with divergent outcome. These transformations were carried out under mild conditions using a low catalyst loading and gave access to a large scope of azido lactones.

STRIGOLACTAM DERIVATIVES AND THEIR USE AS PLANT GROWTH REGULATORS

The present invention relates to novel strigolactam derivatives of formula (I) to processes and intermediates for preparing them, to plant growth regulator compositions comprising them and to methods of using them for controlling the growth of plants and/

Thiol-catalyzed acyl radical cyclization of alkenals

(Chemical Equation Presented) Thiol-catalyzed direct generation of acyl radicals and their intramolecular addition to olefins of alkenals gave 2-substituted five- and six-membered cyclic ketones in reasonably good yields. The combination of odorless tert-dodecanthiol and AIBN or V-40 was the initiator of choice among surveyed radical generators for the cyclization of alkenals. Aldehydes having electron-deficient olefins cyclized more easily than those having unactivated olefins.