112635-43-5

Basic information

• Product Name: Benzene, [2-bromo-1-(bromomethyl)ethenyl]-, (E)-
• CAS NO: 112635-43-5
• Molecular Formula: C9H8Br2
• Molecular Weight: 275.971
• Mol File: 112635-43-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [2-bromo-1-(bromomethyl)ethenyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [2-bromo-1-(bromomethyl)ethenyl]-, (E)-(112635-43-5)
• EPA Substance Registry System: Benzene, [2-bromo-1-(bromomethyl)ethenyl]-, (E)-(112635-43-5)

Safety Data

• Hazardous Substances Data: 112635-43-5(Hazardous Substances Data)

Upstream product

• 98-83-9 isopropenylbenzene 
• 3360-53-0 1-bromo-2-phenyl-1-propene 

Downstream Products

• 112635-47-9 1-((E)-3-Bromo-2-phenyl-allyloxy)-4-methyl-benzene 
• 112635-45-7 C₁₅H₁₃BrO 

Relevant articles and documents

Synthesis of 1-Aryltetralins and 1-Arylnaphthalenes via (4 + 2) Annulation of β-Ketosulfones with Styryl Bromides

A novel route has been developed for the synthesis of various substituted 1-aryltetralins 6 and 1-arylnaphthalenes 8 via (1) K2CO3-mediated α-styrylation of β-ketosulfones 3 with bromostyryl bromides 4 and (2) stereocontrolled NaBH4-promoted reduction of the resulting γ-alkenones 5, followed by BF3·OEt2-catalyzed intramolecular annulation of the corresponding γ-alkenols 7 under rt/5 h and reflux/10 h conditions, respectively. The key structures of 6 and 8 were confirmed by X-ray crystallographic analysis. A plausible mechanism has been proposed.