112655-07-9

Basic information

• Product Name: Carbonic acid (E)-4-methoxycarbonyloxy-5-phenyl-pent-2-enyl ester methyl ester
• Synonyms: Carbonic acid (E)-4-methoxycarbonyloxy-5-phenyl-pent-2-enyl ester methyl ester
• CAS NO: 112655-07-9
• Molecular Weight: 294.304
• Mol File: 112655-07-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbonic acid (E)-4-methoxycarbonyloxy-5-phenyl-pent-2-enyl ester methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid (E)-4-methoxycarbonyloxy-5-phenyl-pent-2-enyl ester methyl ester(112655-07-9)
• EPA Substance Registry System: Carbonic acid (E)-4-methoxycarbonyloxy-5-phenyl-pent-2-enyl ester methyl ester(112655-07-9)

Safety Data

• Hazardous Substances Data: 112655-07-9(Hazardous Substances Data)

Upstream product

• 81454-71-9 (E)-methyl 4-hydroxy-5-phenylpent-2-enoate 
• 139670-25-0 (E)-5-phenylpent-2-ene-1,4-diol 
• 79-22-1 methyl chloroformate 

Downstream Products

• 1007-52-9 (E/Z)-1-benzylbuta-1,3-diene 
• 112655-08-0 ((1E,3E)-5-methoxypenta-1,3-dien-1-yl)benzene 
• 91166-39-1 (E)-penta-2,4-dien-1-ylbenzene 
• 33046-84-3 (2E)-5-phenyl-2-pentenal 

Relevant articles and documents

A novel palladium-catalyzed deoxygenation of enediols to 1,3-dienes

Hydroxylative Knoevenagel condensation of aldehydes followed by reduction provides a simple entry to 1,4-enediols. Subjecting the dicarbonate to a palladium(0) catalyst in the presence of triisopropyl phosphite achieves a mild vinylogous deoxygenation to (E)-1,3-dienes. Stereocontrolled synthesis of the sex pheromone of the red bollworm moth, (E)-9,11-dodecadienyl acetate, and a formal synthesis of the cotton boll weevil antifeedant, α-eleostearic acid, demonstrate the utility of this new methodology.