1126795-32-1Relevant articles and documents
Rearrangement of β-chloro N-oxides to hydroxylamines: Opening of the oxazetidinium intermediate by different nucleophiles
Wefelscheid, Ulrike K.,Woodward, Simon
supporting information; experimental part, p. 2254 - 2256 (2009/08/07)
The rearrangement of β-chloro N-oxides to hydroxylamines is stereospecific in accord with the presence of a cyclic oxazetidinium intermediate. The latter opens with a range of nucleophiles (carboxylates, cyanide, azide, and thiols)