1127405-03-1Relevant articles and documents
Copper-Catalyzed C?N Bond Formation via Oxidative Cross-Coupling of Amines with α-Aminocarbonyl Compounds
Liu, Xing-Xing,Wu, Zhao-Yang,He, Yong-Qin,Zhou, Xiao-Qiang,Hu, Ting,Ma, Chao-Wei,Huang, Guo-Sheng
, p. 2385 - 2391 (2016)
A novel and selective method for the simple copper-catalyzed α-amination of α-aminocarbonyl compounds to afford 2-amino-2-iminocarbonyl and 2-amino-2-oxocarbonyl compounds is reported. This transformation is achieved by C(sp3)?H and N?H bond ox
Pd(triNHC)-catalyzed Double Carbonylation of Aryliodides With Amines: The Effect of triNHC Ligands
Shaik, Baji,Jang, Hye-Young
supporting information, p. 492 - 494 (2020/12/23)
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Cu(OAc)2 and acids promoted the oxidative cleavage of α-aminocarbonyl compounds with amines: efficient and selective synthesis of 2-t-amino-2-imino-carbonyl and 2-amino-2-oxocarbonyl
Chen, De,Cheng, Chaozhihui,Zeng, Sheng,Luo, Yongyue,Zhang, Jiajia,Deng, Wei,Zeng, Zebing,Wang, Ruijia,Xiang, Jiannan
supporting information, (2020/04/15)
A novel and efficient method for the synthesis of 2-t-amino-2-imino-carbonyl (C) and 2-amino-2-oxocarbonyl (D) compounds has been discovered through a copper-promoted oxidating amidation reactions between α-amino -carbonyl compounds and amines. Promoted by the crucial copper species, perfect selectivity and good to excellent yields could be achieved. This transformation is achieved through C[sbnd]N bond oxidative cleavage and formation a novel C[sbnd]N bond. This reaction system has a broad reaction scope, providing a facile pathway for the α-functionalization of α-amino ketones.
