112745-27-4

Basic information

• Product Name: N,N,N',N'-Tetramethylpiperazinium dipicrate
• CAS NO: 112745-27-4
• Molecular Weight: 600.456
• Mol File: 112745-27-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N,N',N'-Tetramethylpiperazinium dipicrate(CAS DataBase Reference)
• NIST Chemistry Reference: N,N,N',N'-Tetramethylpiperazinium dipicrate(112745-27-4)
• EPA Substance Registry System: N,N,N',N'-Tetramethylpiperazinium dipicrate(112745-27-4)

Safety Data

• Hazardous Substances Data: 112745-27-4(Hazardous Substances Data)

Upstream product

• 6952-20-1 N,N,N',N'-Tetramethylpiperazinium diiodide 
• 146-84-9 silver picrate 
• 108-01-0 2-(N,N-dimethylamino)ethanol 
• 364-44-3 picryl fluoride 

Relevant articles and documents

Spirocyclic meisenheimer complexes: XLII. Intramolecular alkylation of O-picryl amino alcohols with a tertiary amino group

Dimethyl(2-picryloxyethyl)-and dimethyl(3-picryloxypropyl)amines do not form zwitterionic spirocyclic 2,4,6-trinitrocyclohexadienide (Meisenheimer) adducts but undergo intramolecular alkylation to give, respectively, tetramethylpiperazinium and dimethylazetidinium picrates. Likewise, spirocyclic trinitrocyclohexadienide complex with a 4-morpholiniomethyl-1,3-dioxolane ring is regioselectively converted into 2-hydroxy-7-oxa-4-azoniaspiro[3.5]nonane picrate whose structure was proved by X-ray analysis.