112863-84-0Relevant articles and documents
The tandem intermolecular hydroalkoxylation/claisen rearrangement
Ketcham, John M.,Biannic, Berenger,Aponick, Aaron
supporting information, p. 4157 - 4159 (2013/06/04)
The Au(i)-catalyzed intermolecular hydroalkoxylation of alkynes with allylic alcohols to provide allyl vinyl ethers that subsequently undergo Claisen rearrangement is reported. This new cascade reaction strategy facilitates the direct formation of γ,δ-unsaturated ketones from simple starting materials in a single step.