112947-63-4

Basic information

• Product Name: 2-Propyn-1-ol, 3-phenyl-1-(trimethylsilyl)-
• CAS NO: 112947-63-4
• Molecular Formula: C12H16OSi
• Molecular Weight: 204.344
• Mol File: 112947-63-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Propyn-1-ol, 3-phenyl-1-(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propyn-1-ol, 3-phenyl-1-(trimethylsilyl)-(112947-63-4)
• EPA Substance Registry System: 2-Propyn-1-ol, 3-phenyl-1-(trimethylsilyl)-(112947-63-4)

Safety Data

• Hazardous Substances Data: 112947-63-4(Hazardous Substances Data)

Upstream product

• 106881-72-5 2,2-Dimethyl-2-silapropanal 
• 4440-01-1 lithium phenylacetylide 

Downstream Products

• 112947-69-0 3-phenyl-1-(trimethylsilyl)-2-propyn-1-one 

Relevant articles and documents

Rapid and Effective Synthesis of α-Acyloxy-α-alkynyltrimethylsilanes

α-Alkynyl-α′-trimethylsilylhydrazones are readily oxidized into diazo compounds under simple experimental conditions. These stable diazo species can in turn react with a range of carboxylic acids via a protonation-nucleophilic substitution sequence, leading to valuable α-acyloxy-α-alkynyltrimethylsilanes. This procedure avoids the delicate preparation and manipulation of α-hydroxypropargyltrimethylsilanes.