113081-88-2

Basic information

• Product Name: Undecanoic acid, 2-acetyl-, methyl ester
• CAS NO: 113081-88-2
• Molecular Formula: C14H26O3
• Molecular Weight: 242.359
• Mol File: 113081-88-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Undecanoic acid, 2-acetyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Undecanoic acid, 2-acetyl-, methyl ester(113081-88-2)
• EPA Substance Registry System: Undecanoic acid, 2-acetyl-, methyl ester(113081-88-2)

Safety Data

• Hazardous Substances Data: 113081-88-2(Hazardous Substances Data)

Upstream product

• 693-58-3 1-Bromononane 
• 105-45-3 acetoacetic acid methyl ester 
• 67-56-1 methanol 
• 143-08-8 nonyl alcohol 
• 51688-56-3 2-acetylundecanoic acid ethyl ester 

Downstream Products

• 1612161-11-1 C₁₅H₂₈O₃ 

Relevant articles and documents

Synthesis and characterization of anaerobic degradation biomarkers of n-alkanes via hydroxylation/carboxylation pathways

Metabolite profiling is a powerful method in research on anaerobic biodegradation of hydrocarbons. Hydroxylation and carboxylation are proposed pathways in anaerobic degradation but very little direct evidence is available about metabolites and signature biomarkers. 2-Acetylalkanoic acid is a potential signature metabolite because of its unique and specific structure among possible intermediates. A procedure for the synthesis of four homologues with various carbon chain lengths was proposed and the characteristics of 2-acetyl-alkanoic acid esters were investigated using four derivatization processes, namely methyl, ethyl, n-butyl and trimethylsilyl esterification. Four intermediate fragments observed were at m/z 73 + 14n, 87 + 14n, 102 + 14n (n = 1, 2 and 4 for methyl, ethyl and n-butyl ester, respectively) and [M - 42]+ for three of the derivatization methods. For silylation, characteristic ions were observed at m/z 73, 117, [M - 42]+ and [M - 55]+ . These are basic and significant data for the future identification of potential intermediates of the hydroxylation and carboxylation pathways in hydrocarbon degradation.

Total synthesis of (±)-trachyspic acid and determination of the relative configuration

The first total synthesis of (±)-trachyspic acid, a tumor cell heparanase inhibitor, was accomplished based on Cr(II)/Ni(II)-mediated reaction of the aldehyde containing the citric acid moiety and the long-chain triflate, and the relative configuration of

A convenient method for the preparation of (Z)-αβ-unsaturated carbonyl compounds

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