113331-87-6

Basic information

• Product Name: Cyclopentanone, 3-hydroxy-4-phenyl-, trans-
• CAS NO: 113331-87-6
• Molecular Formula: C11H12O2
• Molecular Weight: 176.215
• Mol File: 113331-87-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclopentanone, 3-hydroxy-4-phenyl-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopentanone, 3-hydroxy-4-phenyl-, trans-(113331-87-6)
• EPA Substance Registry System: Cyclopentanone, 3-hydroxy-4-phenyl-, trans-(113331-87-6)

Safety Data

• Hazardous Substances Data: 113331-87-6(Hazardous Substances Data)

Upstream product

• 29783-26-4 cis-4-cyclopentene-1,3-diol 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 113331-81-0 (1R^*,4R^*,5S^*)-5-phenyl-2,3-dioxabicyclo<2.2.1>heptane 
• 114738-30-6 (3R^*,4S^*)-3-<(tert-butyldimethylsilyl)oxy>-4-phenylcyclopentan-1-one 

Relevant articles and documents

Stereoselective Synthesis of 3-Hydroxy-4-arylcyclopentanones and 4-Arylcyclopentenones through a Heck-Matsuda Desymmetrization of meso cis-4-Cyclopentene-1,3-diol

A new palladium-catalyzed route to 3-hydroxy-4-arylcyclopentanones and 4-arylcyclopentenones in a diastereo- and enantioselective manner by a Heck-Matsuda desymmetrization was achieved from the commercially available meso cis-4-cyclopentene-1,3-diol. This method is highly practical, mild, high yielding and is carried out under "open vessel" conditions. Protected and unprotected substrates provide distinct products bearing considerable value as synthetic scaffolds for the synthesis of natural and unnatural bioactive compounds containing a five-membered ring.

An Electron Transfer Model for Thromboxane Biosynthesis

Conversion of prostaglandin endoperoxide model compound (1) into the thromboxane B ring system (6a) and (7a) was achieved with the aid of the ferrous ion.