113555-32-1

Basic information

• Product Name: Bicyclo[2.2.0]hexane, 1-bromo- (9CI)
• Synonyms: Bicyclo[2.2.0]hexane, 1-bromo- (9CI)
• CAS NO: 113555-32-1
• Molecular Formula: C₆H₉Br
• Molecular Weight: 161.03966
• Product Categories: HALIDE
• Mol File: 113555-32-1.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 149.6±9.0 °C(Predicted)
• Appearance: /
• Density: 1.667±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Bicyclo[2.2.0]hexane, 1-bromo- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.0]hexane, 1-bromo- (9CI)(113555-32-1)
• EPA Substance Registry System: Bicyclo[2.2.0]hexane, 1-bromo- (9CI)(113555-32-1)

Safety Data

• Hazardous Substances Data: 113555-32-1(Hazardous Substances Data)

Upstream product

• 186-04-9 cis-bicyclo<2.2.0>hexane 
• 75-62-7 Bromotrichloromethane 

Relevant articles and documents

Homolytic Rearrangements of Bicyclohexane and Bicycloheptane

Free radicals abstract hydrogen from both the bridge and bridgehead sites in bicyclohexane (4).The bicyclohexan-1-yl radical was observed by e.p.r. spectroscopy.The bicyclohexan-2-yl radical rearranges by stereoelectronically forbidden β-scission to give cyclohex-3-enyl radicals.Unlike other cyclobutanes, compound (4) undergoes an SH2 reaction with bromine atoms.Free radicals abstract hydrogen only from the methylene groups of the C5 ring in bicycloheptane (15a).The bicycloheptan-2-yl radicals were observed by e.p.r. spectroscopy, as was their rearrangement, by stereoelectronically allowed β-scission, to 2-(cyclopent-2-enyl)ethyl radicals.Bromine atoms abstract hydrogen from (15a) and no SH2 reaction was detected.The radicals and their rearrangements were studied by semi-empirical MINDO/3 and MNDO methods.