113603-28-4

Basic information

• Product Name: 2-Cyclodecene-1-methanol, 7-[(2-methoxyethoxy)methoxy]-4-(1-methylethyl)-1-(phenylthio)-
• CAS NO: 113603-28-4
• Molecular Formula: C24H38O4S
• Molecular Weight: 422.629
• Mol File: 113603-28-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Cyclodecene-1-methanol, 7-[(2-methoxyethoxy)methoxy]-4-(1-methylethyl)-1-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclodecene-1-methanol, 7-[(2-methoxyethoxy)methoxy]-4-(1-methylethyl)-1-(phenylthio)-(113603-28-4)
• EPA Substance Registry System: 2-Cyclodecene-1-methanol, 7-[(2-methoxyethoxy)methoxy]-4-(1-methylethyl)-1-(phenylthio)-(113603-28-4)

Safety Data

• Hazardous Substances Data: 113603-28-4(Hazardous Substances Data)

Upstream product

• 113589-96-1 methyl (2EZ,5R,8RS)-11-hydroxy-8-(2-methoxyethoxymethoxy)-5-(1-methylethyl)-2-phenylthio-2-undeceonate 
• 113603-27-3 (3R,6RS)-9-acetoxy-6-(2-methoxyethoxymethoxy)-3-(1-methylethyl)-nonanal dimethylacetal 
• 113589-94-9 Acetic acid (R)-4-(2-methoxy-ethoxymethoxy)-8-methyl-7-(2-oxo-ethyl)-nonyl ester 
• 113590-02-6 (R)-7-(2,2-Dimethoxy-ethyl)-4-(2-methoxy-ethoxymethoxy)-8-methyl-nonanal 
• 112193-61-0 (R)-2-Allyl-6-(2,2-dimethoxy-ethyl)-7-methyl-3-oxo-octanoic acid methyl ester 
• 113589-93-8 (3R,6RS)-6-(2-methoxyethoxymethoxy)-3-(1-methylethyl)-9-decenal dimethylacetal 
• 113590-03-7 (R)-7-(2,2-Dimethoxy-ethyl)-4-(2-methoxy-ethoxymethoxy)-8-methyl-nonan-1-ol 
• 113590-01-5 (R)-8-(2,2-Dimethoxy-ethyl)-9-methyl-dec-1-en-5-ol 
• 105897-86-7 (R)-3-(1-methylethyl)-6-oxo-9-decenal dimethylacetal 
• 105897-85-6 (R)-3-(1-methylethyl)-6-oxoheptanal dimethylacetal 
• 113589-97-2 methyl (2EZ,5R,8RS)-8-(2-methoxyethoxymethoxy)-5-(1-methylethyl)-2-phenylthio-11-p-toluenesulfonyloxy-2-undeceonate 
• 113589-98-3 methyl (1RS,2E,4S,7RS)-7-(2-methoxyethoxymethoxy)-4-(1-methylethyl)-1-phenylthio-2-cyclodecene-1-ylcarboxylate 

Downstream Products

• 105897-91-4 (1RS,2E,4S,7RS)-7-hydroxy-4-(1-methylethyl)-1-phenylthio-2-cyclodecene-1-methyl benzoate 
• 90460-45-0 (4S,5E)-4-isopropyl-7-methylene-10-phenylthio-5-cyclodecen-1-one 
• 105329-29-1 (4S,5E)-7-methylene-4-(1-methylethyl)-10-phenylsulfinyl-5-cyclodecene-1-one 
• 61228-92-0 (3S,8R,9R,10S)-(-)-periplanone-B 
• 113589-99-4 Benzoic acid (E)-(S)-4-isopropyl-7-(2-methoxy-ethoxymethoxy)-1-phenylsulfanyl-cyclodec-2-enylmethyl ester 

Relevant articles and documents

TOTAL SYNTHESIS OF (-)-PERIPLANONE-B, NATURAL MAJOR SEX-EXCITANT PHEROMONE OF THE AMERICAN COCKROACH, PERIPLANETA AMERICANA

The total synthesis of (-)-periplanone-B 1, the major sex excitant and attractant pheromone of the American cockroach was accomplished starting from (+)-dihydrolimonene 2.Intramolecular alkylation of the substituted α-phenylthioacrylate 10 gave rise to the (E)-cyclodecene 11.Second key reaction was the reductive elimination of vicinal phenylthiobenzoate 14 to provide the cojugated diene 15.Overall yield of 1 through 28 steps was 0.5 percent.