1137895-28-3

Basic information

• Product Name: [HC(C(Me)N(2,6-i-Pr-C6H3))2]Al(H)(μ-O)Si(O-t-Bu)3
• CAS NO: 1137895-28-3
• Molecular Weight: 709.077
• Mol File: 1137895-28-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [HC(C(Me)N(2,6-i-Pr-C6H3))2]Al(H)(μ-O)Si(O-t-Bu)3(CAS DataBase Reference)
• NIST Chemistry Reference: [HC(C(Me)N(2,6-i-Pr-C6H3))2]Al(H)(μ-O)Si(O-t-Bu)3(1137895-28-3)
• EPA Substance Registry System: [HC(C(Me)N(2,6-i-Pr-C6H3))2]Al(H)(μ-O)Si(O-t-Bu)3(1137895-28-3)

Safety Data

• Hazardous Substances Data: 1137895-28-3(Hazardous Substances Data)

Upstream product

• 18166-43-3 tris(tert-butoxy)silanol 
• 501081-97-6 [HC(C(Me)N(2,6-(i)Pr₂C₆H₃))2]Al(SH)2 

Downstream Products

• 1137895-29-4 [HC(C(Me)N(2,6-i-Pr-C6H3))2]Al(SH)(μ-O)Si(O-t-Bu)3 

Relevant articles and documents

Solubilizing functionalized molecular aluminosilicates

Molecular aluminosilicate LAl(SH)(μ-O)Si(OH)(OtBu) 21 (L = [HC{C(Me)N(Ar)}2]-, Ar = 2,6- iPr2C6H3) has been prepared from LAl(SH)22 and (tBuO)2Si(OH)2 in high yield. When reacted with one equiv. of water, the unique aluminosilicate containing two terminal hydroxy groups LAl(OH·THF)(μ-O)Si(OH)(O tBu)23 can be isolated. However, when 2 is reacted with the bulkier silanol (tBuO)3SiOH, no reaction is observed. The desired LAl(SH)(μ-O)Si(OtBu)36 can be prepared in a two-step synthesis between LAlH24 and (tBuO) 3SiOH giving first LAl(H)(μ-O)Si(OtBu)35, which reacts further with elemental sulfur to give 6 as the only product. Direct hydrolysis of 6 was conducted to obtain LAl(OH)(μ-O)Si(OtBu) 37, however, such hydrolysis always resulted in a complete decomposition of the starting material. Therefore we used boric acid, which condenses in non-polar solvents and slowly evolve water, to hydrolyze 6 to 7 under mild conditions. Compounds 1, 3 and 5-7 have been characterized by single-crystal X-ray diffraction. The Royal Society of Chemistry 2009.