114057-41-9Relevant articles and documents
Addition of Dimesitylsilylene to Olefins. A Reinvestigation
Zhang,Wagenseller,Conlin, Amcnd R. T.
, p. 4278 - 4281 (2007/10/02)
We have reinvestigated the report that dimesitylsilylene adds nonstereospecifically to cis- and trans-2-butene. Stereospecific addition of dimesitylsilylene to cis- and trans-2-pentenes and -4-octenes produced the corresponding siliranes. A photoisomerization pathway is also reported for these siliranes. A probable explanation for the earlier and spurious interpretation is given.