114092-09-0

Basic information

• Product Name: 7-exo-<(4-chlorophenylsulfonyl)ethyl>-5-methyl-6,8-dioxabicyclo<3.2.1>octane
• CAS NO: 114092-09-0
• Molecular Weight: 330.832
• Mol File: 114092-09-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 7-exo-<(4-chlorophenylsulfonyl)ethyl>-5-methyl-6,8-dioxabicyclo<3.2.1>octane(CAS DataBase Reference)
• NIST Chemistry Reference: 7-exo-<(4-chlorophenylsulfonyl)ethyl>-5-methyl-6,8-dioxabicyclo<3.2.1>octane(114092-09-0)
• EPA Substance Registry System: 7-exo-<(4-chlorophenylsulfonyl)ethyl>-5-methyl-6,8-dioxabicyclo<3.2.1>octane(114092-09-0)

Safety Data

• Hazardous Substances Data: 114092-09-0(Hazardous Substances Data)

Upstream product

• 114092-02-3 9-(4-chlorophenylthio)nona-1,6-diene 
• 3710-30-3 1,7-Octadiene 
• 114092-11-4 9-(4-chlorophenylsulfonyl)-6,7-epoxynon-1-ene 
• 114092-06-7 9-(4-chlorophenylsulfonyl)non-6-en-2-one 
• 114092-04-5 9-(4-chlorophenylsulfonyl)nona-1,6-diene 
• 104316-84-9 4-chlorophenylthiomethyl trifluoroacetate 
• 934-73-6 methyl 4-chlorophenyl sulfoxide 
• 114092-12-5 (6R,7R)-9-(4-Chloro-benzenesulfonyl)-6,7-dihydroxy-nonan-2-one 
• 114092-08-9 5-{3-[2-(4-Chloro-benzenesulfonyl)-ethyl]-oxiranyl}-pentan-2-one 

Relevant articles and documents

Synthesis of (+/-)-endo- and (+/-)-exo-Brevicomin via Ene Reaction of the Pummerer Rearrangement Product Derived from 4-Chlorophenyl Methyl Sulfoxide

(+/-)-endo- (4) and (+/-)-exo-Brevicomin (5) were synthesized by employing the ene-type reaction of 4-chlorophenylthiomethyl trifluoroacetate (2) as the key step.The ene product 7 was converted, via two steps, into the ketosulfone 9, whose epoxidation fol