1141885-03-1

Basic information

• Product Name: (2S)-4-[(Z)-4-[3-[(R)-1-(1-naphthyl)ethyl]ureido]benzylidene]-2-ethoxytetrahydrofuran
• CAS NO: 1141885-03-1
• Molecular Weight: 416.52
• Mol File: 1141885-03-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S)-4-[(Z)-4-[3-[(R)-1-(1-naphthyl)ethyl]ureido]benzylidene]-2-ethoxytetrahydrofuran(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-4-[(Z)-4-[3-[(R)-1-(1-naphthyl)ethyl]ureido]benzylidene]-2-ethoxytetrahydrofuran(1141885-03-1)
• EPA Substance Registry System: (2S)-4-[(Z)-4-[3-[(R)-1-(1-naphthyl)ethyl]ureido]benzylidene]-2-ethoxytetrahydrofuran(1141885-03-1)

Safety Data

• Hazardous Substances Data: 1141885-03-1(Hazardous Substances Data)

Upstream product

• 1141885-00-8 (Z)-4-(4-aminobenzylidene)-2-ethoxytetrahydrofuran 
• 42340-98-7 (R)-1-(1-naphthyl)ethyl isocyanate 

Relevant articles and documents

Palladium(II)-catalyzed asymmetric coupling of allylic alcohols and vinyl ethers: Insight into the palladium and copper bimetallic catalyst

The use of PdX2, CuX2 (X = OAc, OCOCF3, or Cl), and catechol together with (S,S)-4,4'-bisbenzyl- 2,2'-bioxazoline under O2 induces the asymmetric coupling of cinnamyl alcohols and vinyl ethers to give (R)-(+)-2-alkoxy-4-benzylidenetetrahydrofurans in 40-53% ee (79% yield). The present study provides implications for the so-called Wacker catalyst of PdX2 and CuX2, in terms of that the anionic ligands (X) of Pd and Cu interchange between two metals.