114367-15-6

Basic information

• Product Name: Ni(C₃H₄CH₂CON(C₆H₅))P(C₂H₅)3
• CAS NO: 114367-15-6
• Molecular Weight: 350.063
• Mol File: 114367-15-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ni(C₃H₄CH₂CON(C₆H₅))P(C₂H₅)3(CAS DataBase Reference)
• NIST Chemistry Reference: Ni(C₃H₄CH₂CON(C₆H₅))P(C₂H₅)3(114367-15-6)
• EPA Substance Registry System: Ni(C₃H₄CH₂CON(C₆H₅))P(C₂H₅)3(114367-15-6)

Safety Data

• Hazardous Substances Data: 114367-15-6(Hazardous Substances Data)

Upstream product

• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 103-71-9 phenyl isocyanate 
• 106-99-0 buta-1,3-diene 
• 554-70-1 triethylphosphine 

Relevant articles and documents

STOECHIOMETRISCHE UND KATALYTISCHE CC-VERKNUEPFUNGEN ZWISCHEN 1,3-BUTADIEN UND PHENYLISOCYANAT AN NICKEL(0)-KOMPLEXEN

The CC coupling of 1,3-butadiene with phenylisocyanate at nickel(0) systems is ligand-dependent.Basic phosphanes such as triethyl- or tricyclohexylphosphane induce a stoichiometric 1/1 CC-coupling reaction yielding azanickela complexes.Triphenylphosphane, on the other hand, leads to a catalytic reaction.Catalysis is initiated by 2/1 coupling, which, after intramolecular cyclisation finally yields carbocyclic five-ring amides.Some special features are listed and the reaction mechanisms are discussed.