1144030-76-1

Basic information

• Product Name: [Pd(κ2-N,C-2-phenylquinoline)(triphenylphosphine)(p-toluenesulfonato)]*CH2Cl2
• CAS NO: 1144030-76-1
• Molecular Weight: 829.092
• Mol File: 1144030-76-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(κ2-N,C-2-phenylquinoline)(triphenylphosphine)(p-toluenesulfonato)]*CH2Cl2(CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(κ2-N,C-2-phenylquinoline)(triphenylphosphine)(p-toluenesulfonato)]*CH2Cl2(1144030-76-1)
• EPA Substance Registry System: [Pd(κ2-N,C-2-phenylquinoline)(triphenylphosphine)(p-toluenesulfonato)]*CH2Cl2(1144030-76-1)

Safety Data

• Hazardous Substances Data: 1144030-76-1(Hazardous Substances Data)

Upstream product

• 612-96-4 2-Phenylquinoline 
• 75-09-2 dichloromethane 
• 1145982-29-1 [Pd(κ2-N,C-2-phenylquinoline)(OAc)] 
• 6192-52-5 p-toluenesulfonic acid monohydrate 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

NC palladacycles in the Heck arylation of ethylene: Synthesis, structure and their reactivity

Monomeric cyclopalladated complexes with NC coordination using ligands 2-phenylpyridine, 2-phenylquinoline, 8-methylquinoline have been synthesized and the structures have been determined by single crystal X-ray structure analysis. The crystal structures of monomeric palladacycles prepared using benzophenone oxime, and 2-phenylpyridine have also been determined. The use of these complexes in the Heck arylation of ethylene with 2-bromo-6-methoxynaphthalne (BMN) to give 2-vinyl-6-methoxynapthalene which is an intermediate for the synthesis of anti-inflammatory drug Naproxen has been examined and also arylation of ethylene with 3-bromo-benzophenone and 4-bromo-isobutylbenzene was investigated. These palladacycles with NC coordination show excellent catalytic activity with a TOF > 4000 h-1.