1144099-48-8

Basic information

• Product Name: 3-benzyl-4-triphenyltinoxy-butyramide
• Synonyms: 3-benzyl-4-triphenyltinoxy-butyramide
• CAS NO: 1144099-48-8
• Molecular Weight: 542.265
• Mol File: 1144099-48-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-benzyl-4-triphenyltinoxy-butyramide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-benzyl-4-triphenyltinoxy-butyramide(1144099-48-8)
• EPA Substance Registry System: 3-benzyl-4-triphenyltinoxy-butyramide(1144099-48-8)

Safety Data

• Hazardous Substances Data: 1144099-48-8(Hazardous Substances Data)

Upstream product

• 19340-88-6 N-benzyl-4-hydroxybutanamide 
• 639-58-7 triphenyltin chloride 

Relevant articles and documents

Seven membered ring chelates derived from γ-hydroxyamides and triphenyltin or diphenylboron

N-Benzyl-4-hydroxy-butyramide (1), 4-hydroxy-N-[(R)-1-phenyl-ethyl]-butyramide (2), and (R)-4-hydroxy-2-methyl-N-[(R)-1-phenyl-ethyl]-butyramide (3a) were used to prepare new diphenylboron and triphenyltinoxy compounds: diphenylborinic acid 3-benzylcarbamoyl-propyl ester (4), diphenylborinic acid 3-[(R)-1-phenyl-ethylcarbamoyl]-propyl ester (5) and diphenylborinic acid (R)-3-[(R)-1-phenyl-ethylcarbamoyl]-butyl ester (6), N-benzyl-4-triphenyltinoxy-butyramide (7), 4-triphenyltinoxy-N-[(R)-1-phenyl-ethyl]-butyramide (8), and (R)-4-triphenyltinoxy-2-methyl-N-[(R)-1-phenyl-ethyl]-butyramide (9). The X-ray diffraction analysis of a crystalline structure of the new γ-hydroxyamide 3a is reported, as well as that of the first example of a crystalline structure where a diphenylborinic ester forms a seven membered chelate, by a carbonyl coordination to boron (4). Structural studies of tin and boron esters were performed by NMR. The C{double bond, long}O internal coordination to tin atoms, affording seven membered rings, was observed by 119Sn NMR experiments at low temperature.