114597-27-2

Basic information

• Product Name: hexachlorocyclohexaphosphane
• Synonyms: hexachlorocyclohexaphosphane
• CAS NO: 114597-27-2
• Molecular Weight: 398.561
• Mol File: 114597-27-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: hexachlorocyclohexaphosphane(CAS DataBase Reference)
• NIST Chemistry Reference: hexachlorocyclohexaphosphane(114597-27-2)
• EPA Substance Registry System: hexachlorocyclohexaphosphane(114597-27-2)

Safety Data

• Hazardous Substances Data: 114597-27-2(Hazardous Substances Data)

Upstream product

• 7719-12-2 phosphorus trichloride 

Downstream Products

• 13598-36-2 phosphonic Acid 
• 7803-51-2 phosphan 
• 4552-71-0 hexaphenylcyclohexaphosphane 

Relevant articles and documents

Contributions to the Chemistry of Phosphorus, 188. - Halogen-Substituted Cyclohexaphosphanes: Formation and Properties of (PCl)6 and (PBr)6

Hexachlorocyclohexaphosphane (1) and hexabromocyclohexaphosphane (2) are formed in the partial dehalogenation of phosphorus trichloride and phosphorus tribromide, respectively, by magnesium or lithium hydride in polar solvents.As the first perhalogenated cyclophosphanes they are only stable in diluted solutions at low temperature and could be characterized by means of mass spectrometry and 31P nuclear magnetic resonance.Like the known hexaphenylcyclohexaphosphane, but in contrast to the parent compound P6H6, 1 and 2 have a six-membered phosphorus ring skeleton, which is obviously stabilized by electronegative substituents.