1146-59-4Relevant articles and documents
Modelling nucleophilic substitution at silicon using hypervalent silicon compounds based on urea ligands
Bassindale, Alan R.,Glynn, Simon J.,Taylor, Peter G.,Auner, Norbert,Herrschaft, Bernhard
, p. 132 - 140 (2001)
The X-ray crystal structure of a pentacoordinate silicon compound, 3, with a urea ligand shows partial Si-O bond formation and Si-Cl cleavage. The solution NMR parameters for the related series of compounds with different leaving groups provides structura
A distorted trigonal antiprismatic cationic silicon complex with ureato ligands: syntheses, crystal structures and solid state29Si NMR properties
Schoene, Dana,Gerlach, Daniela,Wiltzsch, Conny,Brendler, Erica,Heine, Thomas,Kroke, Edwin,Wagler, Joerg
experimental part, p. 461 - 467 (2010/05/01)
Insertion of phenyl isocyanate into the Si-N bond of N-(tri methylsilyl)diethylamine yields the N'-silylated N,N-diethylN'-phenylurea 1, which undergoes transsilylation with SiCl4 to yield the C 3-symmetric cationic hexacoordinate si