114809-92-6

Basic information

• Product Name: meso-7,8-bis benzenesulfonyl tetradecane
• Synonyms: meso-7,8-bis benzenesulfonyl tetradecane
• CAS NO: 114809-92-6
• Molecular Weight: 478.717
• Mol File: 114809-92-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: meso-7,8-bis benzenesulfonyl tetradecane(CAS DataBase Reference)
• NIST Chemistry Reference: meso-7,8-bis benzenesulfonyl tetradecane(114809-92-6)
• EPA Substance Registry System: meso-7,8-bis benzenesulfonyl tetradecane(114809-92-6)

Safety Data

• Hazardous Substances Data: 114809-92-6(Hazardous Substances Data)

Upstream product

• 52075-21-5 phenyl heptyl sulfone 

Downstream Products

• 10374-74-0 tetradec-7-ene 

Relevant articles and documents

Formation of symmetrical alkenes by homocoupling of metallated sulfones under nickel catalysis

Summary -Allylic sulfones undergo a coupling reaction with organometallic compounds (Mg or Li) not only with copper catalysts but also with iron or nickel salts. With 7,7-disubstituted allylic sulfones and also saturated aliphatic sulfones, however, another reaction was observed whereby two molecules of the starting sulfone are coupled to give symmetrical alkenes. The scope of this reaction was investigated. Elsevier.

DIMERISATION OXIDANTE D'ANIONS DE SULFONES

Cupric salts, particularly triflates, convert α-sulphonyl carbanions into α-disulphones.Allylphenylsulphones couple preferentially in the 3-3 'mode.