1149343-34-9Relevant articles and documents
Effects of electron-deficient β-diketiminate and formazan supporting ligands on copper(I)-mediated dioxygen activation
Hong, Sungjun,Hiii, Lyndal M. R.,Gupta, Aalo K.,Naab, Benjamin D.,Gllroy, Joe B.,Hicks, Robin G.,Cramer, Christopher J.,Tolman, William B.
, p. 4514 - 4523 (2009/09/24)
Copper(I) complexes of a diketiminate featuring CF3 groups on the backbone and dimethylphenyl substituents (4) and a nitroformazan (5) were synthesized and shown by spectroscopy, X-ray crystallography, cyclic voltammetry, and theory to contain copper(l) sites electron-deficient relative to those supported by previously studied diketiminate complexes comprising alkyl or aryl backbone substituents. Despite their electron-poor nature, oxygenation of LCu(CH3CN) (L = 4 or 5) at room temperature yielded bis(hydroxo)dicopper(II) compounds and at -80 0C yielded bis(w-oxo)dicopper complexes that were identified on the basis of UV-vis and resonance Raman spectroscopy, spectrophotometric titration results (2:1 Cu/02 ratio), electron paramagnetic resonance spectroscopy (silent), and density functional theory calculations. The bis(w-oxo)dicopper complex supported by 5 exhibited unusual spectroscopic properties and decayed via a novel intermediate proposed to be a metallaverdazyl radical complex, findings that highlight the potential for the formazan ligand to exhibit "noninnocent" behavior.
