115055-21-5Relevant articles and documents
Designable synthesis of nanocomposite hydrogels with excellent mechanical properties based on chemical cross-linked interactions
Wu, Yongtao,Xia, Mengge,Fan, Qingqing,Zhu, Meifang
, p. 7790 - 7792 (2010)
A new type of nanocomposite hydrogels based on covalent cross-linked interactions with excellent mechanical properties and good stability has been prepared by using in situ free-radical polymerization; polystyrene nanoparticles with photo-activity are used as the cross-linking agent. The Royal Society of Chemistry.
Method for preparing polymerizable photoinitiators
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Paragraph 0019; 0020, (2016/11/17)
The invention discloses a method for preparing polymerizable photoinitiators. The polymerizable photoinitiators are prepared from methacrylic acid and 2-hydroxyl-4'-(2'-hydroxyethoxy)-2-methyl propiophenone by the aid of direct esterification processes. The use quantity of polymerization inhibitors in a reaction system accounts for 0.01%-0.5% of the mass of the methacrylic acid, the use quantity of methane sulfonic acid which is a catalyst accounts for 0.1%-2% of the mass of the methacrylic acid, and a molar proportion of the methacrylic acid to the 2-hydroxyl-4'-(2'-hydroxyethoxy)-2-methyl propiophenone is 1:1-1.2. Each polymerization inhibitor is methoxyphenol or hydroquinone or 2-tertiary butylhydroquinone, and a solvent is toluene or dimethylformamide or tetrahydrofuran. The method has the advantages that the polymerizable photoinitiators are excellent in compatibility with monomers and resin in photo-curing systems fragments obtained after the polymerizable photoinitiators are subjected to illumination pyrolysis are low in migration rate in cured films and are anti-yellowing, excellent initiation effects can be realized, and the method can be applied to the field of photo-cured coating, printing ink, adhesive and the like; the method for synthesizing the polymerizable photoinitiators is low in cost, processes for preparing the polymerizable photoinitiators are simple and convenient, and obvious application effects can be realized.