115160-05-9Relevant articles and documents
2,4,6-Trisphenyl, a New Sterically Demanding Group for Kinetic Stabilization of Unstable Compounds
Okazaki, Renji,Unno, Masafumi,Inamoto, Naoki
, p. 2293 - 2294 (1987)
The titled group (Ar) has been found to be very efficient for kinetic stabilization of a highly reactive N-thiosulfinyl group.The synthesis and the thermal and photochemical behavior of Ar-N=S=s are described.
SYNTHESIS AND REACTIONS OF NOVEL ORGANOSULFUR COMPOUNDS HAVING A HIGHLY STERICALLY BULKY GROUP, 2,4,6-TRISPHENYL
Tokitoh, Norihiro,Takahashi, Masaki,Matsumoto, Tsuyoshi,Suzuki, Hiroyiki,Matsuhashi, Yasusuke,Okazaki, Renji
, p. 161 - 164 (2007/10/02)
Novel cyclic metallatetrasulfides containing Group 14 metals have been synthesized by the thermal reactions of the corresponding metal hydrides substituted by the title new steric protection group.The structure of newly obtained metallacyclopolysulfides is of great interest in comparison with that of the previously reported di-?-cyclopentadienylmetal pentasulfides of titanium(IV) and vanadium(IV).Attempts to prepare the metal-sulfur double bond compounds from the metallacyclopolysulfides are also described.