115234-31-6

Basic information

• Product Name: (6E,12Z)-14-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-4-methyl-3-oxo-tetradeca-6,12-dienoic acid methyl ester
• CAS NO: 115234-31-6
• Molecular Weight: 536.784
• Mol File: 115234-31-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (6E,12Z)-14-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-4-methyl-3-oxo-tetradeca-6,12-dienoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (6E,12Z)-14-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-4-methyl-3-oxo-tetradeca-6,12-dienoic acid methyl ester(115234-31-6)
• EPA Substance Registry System: (6E,12Z)-14-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-4-methyl-3-oxo-tetradeca-6,12-dienoic acid methyl ester(115234-31-6)

Safety Data

• Hazardous Substances Data: 115234-31-6(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 115234-26-9 (Z)-8,8-Dimethoxy-oct-2-enoic acid methyl ester 
• 115234-27-0 (Z)-8,8-Dimethoxy-oct-2-en-1-ol 
• 115234-28-1 tert-Butyl-((Z)-8,8-dimethoxy-oct-2-enyloxy)-diphenyl-silane 
• 115234-29-2 (Z)-8-(tert-Butyl-diphenyl-silanyloxy)-oct-6-enal 
• 30414-53-0 methyl propanoyl acetate 
• 115234-30-5 (2E,8Z)-10-(tert-Butyl-diphenyl-silanyloxy)-deca-2,8-dienal 

Downstream Products

• 115234-32-7 (6E,12Z)-14-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-3-oxo-5-(tetrahydro-pyran-2-yloxy)-tetradeca-6,12-dienoic acid methyl ester 

Relevant articles and documents

Synthesis and transannular Diels-Alder reaction of a cis-trans-trans and trans-cis-cis 13-membered macrocyclic trienone

The synthesis of the cis-trans-trans 5 and trans-cis-cis 6 macrocyclic trienones from cyclohexene is described.Upon heating at 300 deg C, trienone 5 underwent 1,5-H shift and transannular Diels-Alder reaction to give adducts 33, 34 and 35 while trienone 6