115400-59-4Relevant articles and documents
Visible-Light-Triggered, Metal- and Photocatalyst-Free Acylation of N-Heterocycles
Guillemard, Lucas,Colobert, Fran?oise,Wencel-Delord, Joanna
supporting information, p. 4184 - 4190 (2018/09/25)
A photoinduced acylation of N-heterocycles is explored. This visible-light triggered reaction occurs not only under extremely mild reaction conditions, but also does not require the presence of a photosensitizer. The mechanistic studies suggest formation of EDA complexes prompt to harness the energy from visible-light. Compatibility with a large panel of α-keto acids as acyl precursors and an array of N-heterocycles clearly showcase the synthetic potential of this handy and green acylation protocol. (Figure presented.).
Synthesis method of acylated quinoline or isoquinoline derivative
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Paragraph 0060-0064, (2019/07/29)
The invention discloses a synthesis method of an acylated quinoline or isoquinoline derivative, belongs to the field of organic synthesis, and aims to solve the problems of complicated reaction, severe conditions and low environmental friendliness in the
POLAR EFFECTS IN FREE-RADICAL REACTIONS. NEW CATALYTIC PROCESSES IN THE SUBSTITUTION OF HETEROATOMIC BASES BY NUCLEOPHILIC FREE-RADICALS
Minisci, Francesco,Vismara, Elena,Fontana, Francesca,Redaelli, Daniele
, p. 363 - 368 (2007/10/02)
New catalytic hydroxymethylation, dioxanylation and acylation of protonated heteroatomic bases by methanol, dioxan, and aldehydes, respectively, are reported.The importance of the polar effects in determining reactivity, selectivity, and catalytic efficie