115407-74-4

Basic information

• Product Name: (Mn(OOCNHPh)2)n
• CAS NO: 115407-74-4
• Molecular Weight: 327.198
• Mol File: 115407-74-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Mn(OOCNHPh)2)n(CAS DataBase Reference)
• NIST Chemistry Reference: (Mn(OOCNHPh)2)n(115407-74-4)
• EPA Substance Registry System: (Mn(OOCNHPh)2)n(115407-74-4)

Safety Data

• Hazardous Substances Data: 115407-74-4(Hazardous Substances Data)

Upstream product

• 73138-26-8 manganocene 
• 62-53-3 aniline 

Relevant articles and documents

Incorporation and Deoxygenation of Carbon Dioxide: A Metal-Assisted Facile Conversion of Carbon Dioxide and Primary Amines to Isocyanates

Metal N-alkylcarbamato complexes (M = Na, n = 1; M = Mn, Co, n =2) were prepared by treating CO2 with a primary amine RNH2 (R = Ph, Cy, Pr) and various complex precursors.For M = Mn or Co and R = Cy, MCl2 can be used as starting material.These complexes were readily decomposed by acyl halides R'COCl (R' = Ph, Me), and two reaction pathways were observed.One led to decarboxylation and formation of amides RNHC(O)R', while the other afforded isocyanate RNCO and carboxylic acid (M = Na) or carboxylic anhydride (M = Mn, Co).Analysis of the reaction products showed that the metal plays a major role in the formation of the isocyanate, intercepting one of the reaction products.A mechanistic rationalization is proposed.