115423-55-7Relevant articles and documents
The Rearrangement of ortho-Nitrobenzylidenemalonate Derivatives in Reactions with Amines. Applications to Organic Synthesis
Kinastowski, Stefan,Wnuk, Stanislaw,Kaczmarek, Elzbieta
, p. 111 - 118 (2007/10/02)
Rearrangement of 2,4-dinitro-, and 2,4,6-trinitrobenzylidenemalonates in reactions with primary, secondary and tertiary amines, both in the presence and in the absence of alcohols to give 2-amino-4-nitro-, and 2-amino-4,6-dinitrobenzoic acid derivatives is described.Depending on the reaction conditions, various rearrangement products, e.g. ester, ether, amide, are obtained selectively.