115432-05-8Relevant articles and documents
CHELATION CONTROLLED REGIOSELECTIVE ALKYLATION AND 1,4 CHIRALITY TRANSFER IN OPTICALLY ACTIVE 1-ALKOXY-1,4-CYCLOHEXADIENES
Stanssens, Dirk,Keukeleire, Denis De,Vandewalle, Maurits
, p. 4195 - 4198 (2007/10/02)
Chelation controlled alkylation of optically active 1-alkoxy-1,4-cyclohexadienes leads to a mixture of 1,4-cyclohexadienes 4a-c and 1,3-cyclohexadienes 5a-c.The regio- and diastereoselectivities depend upon the nature of the chiral auxiliary and the react