1158483-15-8

Basic information

• Product Name: 1,3,5-tris((allyloxy)methyl)benzene
• Synonyms: 1,3,5-tris((allyloxy)methyl)benzene
• CAS NO: 1158483-15-8
• Molecular Weight: 288.387
• Mol File: 1158483-15-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,3,5-tris((allyloxy)methyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-tris((allyloxy)methyl)benzene(1158483-15-8)
• EPA Substance Registry System: 1,3,5-tris((allyloxy)methyl)benzene(1158483-15-8)

Safety Data

• Hazardous Substances Data: 1158483-15-8(Hazardous Substances Data)

Upstream product

• 51580-41-7 allyl propargyl ether 
• 4464-18-0 1,3,5-tris(hydroxymethyl)benzene 
• 106-95-6 allyl bromide 
• 18226-42-1 1,3,5-Tris(bromomethyl)benzene 
• 107-18-6 allyl alcohol 

Downstream Products

• 1158483-17-0 (-)-(R)-1,3,5-tris(1-allyloxy-2-phenylethyl)benzene 
• 1158483-20-5 (+)-(S)-1,3,5-tris(1-allyloxy-2-phenylethyl)benzene 

Relevant articles and documents

Iron-catalyzed regioselective cyclotrimerization of alkynes to benzenes

We report the synthesis and characterization of simple di(aminomethyl)pyridine ligated iron-pincer complexes, which catalyzed the regioselective [2+2+2] cyclotrimerization of terminal aryl and alkyl alkynes to provide the 1,2,4-trisubstituted benzene molecules. Interestingly, internal alkynes also exhibited similar cyclization and resulted in hexa-substituted benzene compounds. Increased steric bulk on pincer ligands diminished the selectivity for cycloaddition. Cyclotrimerization reactions proceeded at room temperature upon activation of catalyst by a Grignard reagent. EPR studies indicated thermally induced spin crossover effect in catalyst.

Synthesis of enantioenriched secondary and tertiary alcohols via tricarbonylchromium(0) complexes of benzyl allyl ethers

Allyl ethers of the tricarbonylchromium(0) complexes of benzylic alcohols undergo highly enanlioselective benzylic funclionalisation using a chiral base/electrophilic quench sequence; the allyl group is readily removed to reveal a hydroxy group as demonst