115865-86-6Relevant articles and documents
Reaction of Bis(trimethylsilyl) Sulfate with Hexamethyldisalazane, Acetamide, and Guanidine Hydrochloride
Belousova,Vlasova,Voronkov
, p. 397 - 399 (2007/10/03)
Bis(trimethylsilyl) sulfate acts as a donor of trimethylsilyl group in the reaction with hexamethyldisilazane, which results in formation of tris(trimethylsilyl)amine. In the reaction with acetamide it acts as a donor of SO3. The latter inserts into the O-H bond of the imide form of acetamide; the final reaction products are acetonitrile and sulfuric acid. The reaction of bis(trimethylsilyl) sulfate with guanidine hydrochloride leads to trimethylchlorosilane and guanidine sulfate.