1160942-82-4

Basic information

• Product Name: 3-diphenylphosphinoylbutan-1-ol
• CAS NO: 1160942-82-4
• Molecular Weight: 274.299
• Mol File: 1160942-82-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-diphenylphosphinoylbutan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-diphenylphosphinoylbutan-1-ol(1160942-82-4)
• EPA Substance Registry System: 3-diphenylphosphinoylbutan-1-ol(1160942-82-4)

Safety Data

• Hazardous Substances Data: 1160942-82-4(Hazardous Substances Data)

Upstream product

• 75-21-8 oxirane 
• 1733-57-9 ethydiphenylphosphine oxide 

Downstream Products

• 89625-15-0 2-diphenylphosphinoyl-4-hydroxy-2-methyl-1-phenylbutan-1-one 
• 89625-18-3 erythro-2-diphenylphosphinoyl-2-methyl-1-phenylbutane-1,4-diol 
• 89625-18-3 threo-2-diphenylphosphinoyl-2-methyl-1-phenylbutane-1,4-diol 
• 89625-13-8 Benzoic acid 3-(diphenyl-phosphinoyl)-butyl ester 
• 89625-18-3 2-Diphenylphosphinoyl-2-methyl-1-phenylbutane-1,4-diol 

Relevant articles and documents

SYNTHESIS OF SINGLE ISOMERS (E OR Z) OF UNSATURATED ALCOHOLS BY THE HORNER-WITTIG REACTION

Single isomers (E or Z) of homoallylic and higher alcohols can be synthesised from ω-hydroxyalkyldiphenylphosphine oxides and aldehydes, or from alkyldiphenylphosphine oxides and lactones

SYNTHESIS OF E-HOMOALLYLIC ALCOHOLS, γ-HYDROXYKETONES, AND CYCLOPROPYL KETONES FROM 3-DIPHENYLPHOSPHINOYL (Ph2PO) PROPANOLS BY ACYL TRANSFER

Carboxyl transfer (O*C) on 3-Ph2PO propyl esters (9) gives an intermediate (10) from which the Ph2PO group may be removed by the Horner-Witting reaction or by Ph2PO transfer (C*O) to give the title compounds.