116119-12-1

Basic information

• Product Name: 6-Octene-1,3-diol, 3,7-dimethyl-, 1-(4-methylbenzenesulfonate), (3R)-
• CAS NO: 116119-12-1
• Molecular Formula: C17H26O4S
• Molecular Weight: 326.457
• Mol File: 116119-12-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 6-Octene-1,3-diol, 3,7-dimethyl-, 1-(4-methylbenzenesulfonate), (3R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Octene-1,3-diol, 3,7-dimethyl-, 1-(4-methylbenzenesulfonate), (3R)-(116119-12-1)
• EPA Substance Registry System: 6-Octene-1,3-diol, 3,7-dimethyl-, 1-(4-methylbenzenesulfonate), (3R)-(116119-12-1)

Safety Data

• Hazardous Substances Data: 116119-12-1(Hazardous Substances Data)

Upstream product

• 121401-06-7 Toluene-4-sulfonic acid <3-methyl-3-(4-methylpent-3-enyl)oxiran-2-yl>methyl ester 
• 106-24-1 Geraniol 
• 82188-73-6 (2S,3S)-2,3-epoxygeraniol 
• 50727-94-1 (2R,3R)-3-methyl-3-(4-methyl-3-pentenyl)oxiranemethanol 
• 76936-25-9 (-)-(R)-3,7-Dimethyloct-6-en-1,3-diol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 250139-17-4 5-((R)-3-Hydroxy-3,7-dimethyl-oct-6-enyl)-2,3-dimethyl-benzene-1,4-diol 
• 250139-14-1 Acetic acid 5-((R)-3-acetoxy-1-isopropylsulfanyl-3,7-dimethyl-oct-6-enyl)-4-hydroxy-2,3-dimethyl-phenyl ester 
• 132298-89-6 (10E,14E)-(6R,7S)-16-(benzyloxy)-6-(methoxymethoxy)-2,6,10,15-tetramethylhexadeca-2,10,14-trien-7-ol 
• 96304-92-6 teurilene 
• 122554-84-1 (2E,6E)-(10S,11R)-10,11-bis(methoxymethoxy)-2,7,11,15-tetramethyl-1-(phenylthio)hexadeca-2,6,14-triene 
• 122554-81-8 (2E,6E)-(10S,11R)-1-(benzyloxy)-10,11-bis(methoxymethoxy)-2,7,11,15-tetramethylhexadeca-2,6,14-triene 

Relevant articles and documents

First enantioselective total synthesis of the endogenous natriuretic agent LLU-α

The endogenous natriuretic agent LLU-α, 1, has been synthesized from geraniol 4 in 13 steps and 18% overall yield. The two key steps are a Gassman-Sato process to give the phenol 8 and cyclization of the triol 10 with acid to give the chroman 12 with retention of configuration at the tertiary alcohol center. Final oxidation gave 1.